Bird Deterrent Glass Coatings

ABSTRACT

This invention pertains to UV-absorbing coatings that may optionally be covered with an anti-reflective layer and that are applied to exterior-facing surfaces such as a window or other glass surface that are transparent or translucent. Such coatings are visible to various species of birds, but are generally transparent to humans. The UV absorbing coatings have a silane- or silane-derived chromophore or a combination of a silane- or siloxane-based material and a chromophore, which chromophores absorb UV light at about 300 to about 400 nm. More particularly, the silane- or siloxane-based chromophore is 2-hydroxy-4-(3-triethoxysilylpropoxy) diphenylketone or a derivative thereof.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority to U.S. Provisional Patent ApplicationSer. No. 60/764,969, filed Feb. 3, 2006 entitled “Bird Derrent GlassCoatings.”

BACKGROUND OF THE INVENTION

Ornithologists estimate that up to one billion birds are killed eachyear by collisions with windows. These birds inadvertently fly into andcollide with windows and glass panes in homes and commercial buildings.These collisions usually involve small songbirds; such as finches, thatmay fall unnoticed to the ground. The collisions are due primarily tothe transparent and reflective nature of glass. In the case oftransparent glass, birds see an open path, and in the case of reflectiveglass, birds see images that appear as a mirror showing familiar escaperoutes and possible safety zones, and thus, birds fly unaware into thewindow or other glass surface. The speed and force of such an impact cancause instant death of birds. If birds do not die from such impact, theycan be left stunned or fatally injured as a result of brain hemorrhagesor other internal bleeding.

Bird deaths of this nature have a detrimental environmental impact.Unlike many other environmental problems, there is no apparentoffsetting benefit to humans of such deaths. While many bird deathscould be prevented, this problem has received little public attention,and remains largely unrecognized. Klem, D. Jr., “Presentation at NorthAmerican Ornithological Conference,” St. Louis (Apr. 8, 1998).

Concerned groups, such as the National Audubon Society, have suggestedways to reduce bird deaths resulting from window collisions. Suchsuggestions include placing decals, objects, or netting on or in frontof windows to create an interference pattern to reduce the mirror effectof reflective windows and/or to make transparent windows more visible.However, this can be difficult to do over an entire window or buildingof windows, and can be unsightly in appearance to homeowners or businessowners. Glass may also be tilted, which may provide a temporary, but nota permanent solution. Other proposed solutions include providing glassfrits to window or glass panes, so that the window has granules fusedthereon to create a frost-like pattern to reduce reflectivity andtransparency. However, this is generally cumbersome and can beaesthetically unappealing. Finally, films, such as translucent plasticsheets may be placed on windows to give a more solid appearance.However, this is also not practical on a large scale, can beaesthetically unappealing, and typically will significantly limitvisibility to humans.

Other previous attempts to solve the problem of bird collisions are alsoknown. For example, one attempt includes a feather assembly that is madeof a length of line including a plurality of brightly colored featherssecured to the line at spaced locations. The line is secured over aglass window in an attempt to prevent bird collisions. Pulse radiationdevices have also been used to warn birds of potential hazards such aswind turbine electrical generators. The National Audubon Society's hassuggested the use of decals in the shape of spider webs for use withtransparent windows. Other similar decals are commercially availablefrom WindowAlert™ of Bend, Oreg. Such decals contain a component thatpurports to reflect UV sunlight and to act as a neon stoplight forbirds. Even if such decals may potentially make a window appear as asolid object without obscuring a human's ability to see through glass,they usually cover only a fraction of a window's surface, leaving therest of the glass exposed to flying birds. Thus, such decals, to theextent they may be effective, address only part of the problem. Suchdecals also are not completely transparent or invisible to humans, anddo not absorb ultraviolet (UV) light. As a result, they do not appear tobe a satisfactory solution to the problems resulting from thetransparency of glass over the visual spectrum of birds, the reflectivenature of glass and the appearance of bright lights within buildings.

Coatings are known in the art that absorb UV light. They include agentsderived from silicones and methoxy-substituted benzophenones as well asorganopolysiloxane protective coatings that may contain light absorbingagents. Such coatings, however, are generally directed toward plasticmaterials to provide UV and scratch resistance.

It is known that many bird species can discriminate wavelengths of lightin the near-UV range, which wavelengths are smaller than the thresholdwavelengths observable by humans, typically about 400 nm. This isbecause while humans.have three types of photoreceptive cones, birdshave an extra cone for quadchromatic color vision. These cones expandtheir visible light spectrum. Bird eyes, on average, account for about15% of the mass of the bird's entire head, while human eyes, incontrast, account for less than about 2% of a human head. Furthermore,bird retinas, in contrast to those of humans, do not contain bloodvessels, which prevents light scattering such that birds have greatervisual acuity activity than humans.

In view of the visual differences between birds and humans and the lackof a satisfactory solution in the art to the problem of bird collisionswith windows or other glass surfaces to successfully prevent thesignificant level of bird deaths, there exists a need in the art forcoatings, such as the UV-absorbent coatings described herein which mayalso be anti-reflective, for windows or other transparent or translucentglass surfaces that are visible to birds, but not to humans. By applyingsuch coatings to windows or other transparent or translucentexterior-facing surfaces, as described herein, such UV-absorbentcoatings provide sufficient optical absorption to make them visible tobirds, but not to humans, and birds may be deterred from flying intowindows.

BRIEF SUMMARY OF THE INVENTION

The invention includes a UV-absorbing coating capable of deterring birdsfrom collision with a substrate having the coating thereon comprising,at least one of: (a) a silane- or siloxane-based chromophore capable offorming stable bonds with a substrate, and absorbing light at about 300nm to about 400 nm; and (b) a composition comprising a silane and/or asiloxane and a chromophore, wherein the silane and/or siloxane iscapable of forming stable bonds with a substrate, and the chromophore iscapable of absorbing light at about 300 nm to about 400 nm, wherein theUV absorbing coating is visible to birds appears generally transparentto humans.

A method of preventing birds from colliding with a substrate is alsoincluded within the invention which method comprises applying to atleast a portion of a substrate a UV-absorbing coating. The UV-absorbingcoating comprising at least one of: (a) a silane- or siloxane-basedchromophore capable of forming stable bonds with a substrate, andabsorbing light at about 300 nm to about 400 nm; and (b) a compositioncomprising a silane and/or a siloxane and a chromophore, wherein thesilane and/or siloxane is capable of forming stable bonds with asubstrate, and the chromophore is capable of absorbing light at about300 nm to about 400 nm. The substrate having the coating applied thereonis visible to birds, but generally transparent to humans.

In one embodiment, the invention includes a coated substrate capable ofdeterring birds from collision with a substrate having the coatingthereon. The coated substrate comprises at least one of: (a) a silane-or siloxane-based chromophore capable of forming stable bonds with asubstrate, and absorbing light at about 300 nm to about 400 nm; and (b)a composition comprising a silane and/or a siloxane and a chromophore,wherein the silane and/or siloxane is capable of forming stable bondswith a substrate, and the chromophore is capable of absorbing light atabout 300 nm to about 400 nm. The coated substrate is visible to birds,but generally transparent to humans.

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

FIG. 1 is a graphical representation depicting the differences in thevisual acuity of birds and humans, as illustrated by a probableabsorption spectra for swallows and humans.

FIG. 2 is a UV absorption spectragraph of2-hydroxy-4-(3-triethoxysilylpropoxy) diphenylketone in tetrahydrofuransolution.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to the field of UV-absorbing coatings fortransparent or translucent exterior surfaces including windows and otherglass treatments, which coatings are also preferably anti-reflective andUV-absorbing coatings. The invention includes within its scope suchcoatings, as well as a method for preventing birds from colliding with asubstrate using such coatings and substrates coated with such coatings.The UV-absorbing coating of this invention is a silane- orsiloxane-based coating that may include a silane- or siloxane-basedchormophore component and/or a composition comprising a silane- orsiloxane-based component and a chromophore. The silane- orsiloxane-based chromophore and the chormophore used in any silane- orsiloxane-based composition is preferably one that absorbs in the rangeof about 300 nm to about 400 nm, and more particularly in the range fromabout 325 nm to about 400 nm.

The preferred silane- or siloxane-based chromophore is preferably ahydroxy diphenylketone or a derivative thereof. If a chromophore isadded independently to a silane- or siloxane-based composition, it maybe any choromophore which is compatible with the composition and whichpreferably absorbs light in the wavelength regions noted above.

The UV absorbing coating preferably includes either a silane- orsiloxane-based chromophore or other silane- or siloxane-based component(for use with an independent choromophore additive) is also preferablycapable of forming stable bonds with a substrate such as glass, windowsor other transparent or translucent substrates.

The UV-absorbing coating may be used to coat various substratesincluding any transparent or translucent interior or exterior surface,such as, without limitation windows and other glass surfaces, andpreferably including, but not limited to, silicon-based materials orother siliceous substrates. The coating solution can be applied eitheruniformly and/or completely over the substrates or partially, includingfor example, in patterns such as stripes or other similarconfigurations. Such stripes or patterns can be of a wide variety ofsizes and shapes so long as they serve the intended purpose. Coatingsaccording to the present invention are preferably capable of formingdurable chemical bonds to such preferred substrates and are able toremain generally, and preferably substantially completely or completelytransparent in the range of human visual acuity while remaining visibleto various bird species.

In a preferred embodiment an anti-reflective coating is applied to theexterior facing surface of the UV-absorbing coating. Preferably suchanti-reflective coating is on the exterior facing surface regardless ofwhether the UV-absorbing coating is applied to the exterior- orinterior-facing surface of the substrate. As used herein,“interior-facing” and “exterior-facing” are used to indicate directionstoward and away from the exterior of a building or other outsidestructure exposed to flying birds.

Transparent or translucent substrates such as windows and other glasstreatments that are coated in this manner are capable of deterring birdsfrom flying into them and of preventing bird death by absorbing, notmerely reflecting, UV light, which may extend into the range of about425 nm. These deep purple wavelengths are barely observable by humans,but are observable by birds. A UV spectrum illustrating the differencesin the visual acuity of birds and humans is depicted in FIG. 1.Wavelengths A, B and C in the Human spectra exceed this deep purplewavelength as does wavelengths a, b and c in the Bird spectra. However,wavelength d in the Bird spectra is within this wavelength rangeallowing the coating to be visual to birds but not humans.

The silane- or siloxane-based coating of the present invention may bedirectly applied to transparent or translucent exterior-facing orinterior-facing surfaces. In one preferred embodiment, the silane- orsiloxane-based material is a chromophore, and the group providing thechoromophore is preferably bound to silicon in the molecule. Thechromophore group and/or the chormophore provided if an independentchromophore is added to a composition in the UV-coating preferablyabsorbs UV light at from about 300 nm to about 400 nm. Othersubstitutions on the silicon atoms in the chromophore may be provided toallow reaction with silicious substrates and/or to facilitatepolymerization and/or resin-forming reactions for binding the silane- orsiloxane-based material to other similar molecules and/or to thesubstrate.

The silane- and/or siloxane-based UV-absorbing coatings of the presentinvention may be applied to various transparent or translucent substratesurfaces using varying techniques known or to be developed in the art.For example, the coating may be applied to such a surface using resinand/or polymer coating techniques, including reacting the compoundthrough solvent or other coating techniques such that it polymerizes insitu, or by incorporating the silane- or siloxane-based materials and/orany additional chromophores in a composition which may be applied as awax, polish or other composition to the surface. In addition, thecoatings may be applied by dip-coating techniques well known in the artof UV-absorbing and/or antiflective coating application using solventsand/or sol-gel techniques. Alternatively, the components of the coatingsherein may be suspended in an aerosol or similar airborne solution andsprayed onto the substrate surface as an aerosol spray. The silane- orsiloxane-based material once sprayed-on the substrate then polymerizesto the substrate surface forming stable bonds thereon. Further, it iswithin the scope of the invention to provide the coatings to a flexiblefilm substrate such as a transparent or translucent polyolefin orpolyvinyl-based film, such as Mylar, such that the films may be thenapplied to an exterior-facing surface using standard film applicationtechniques including providing an adhesive layer to the back surface ofthe film, applying adhesive to the film or surface prior to applicationand/or static bonding techniques.

Such sprays or resin/polymer-based coatings, dip coating formulations(which should be primarily solvent based prior to drying), waxes,polishes or films having coatings thereon, may contain additives withinthe coatings or coating composition which are known or to be developedin the anti-reflective and/or UV-absorbing coating arts for physical orlight property modification such as, but not limited to anti-slipagents, surfactants, fire retardants, antioxidants, age resistingagents, plasticizers, tackifiers, silane coupling agents, mildewproofingagents, release agents, disperants, flatting agents, heat stabilizers,light stabilizers, wetting agents, extenders, thixotropic agents,viscosity modifiers, lubricants, impact modifiers, tougheners, colorantssuch as dyes and pigments (to the extent they do not otherwise interferewith the purpose of the invention herein), clarifying agents, solvents,propellants and/or waxes. Such additives may be provided in amountstypically used in the art and preferably collectively make up no greaterthan 50 percent by weight of the resulting coating and no more thanabout 30 percent by weight of the coating composition. The componentsmay be combined and/or the coatings applied using any suitabletechniques known or to be developed in the art.

The coatings of the present invention preferably include at least onesilane- or siloxane-based chromophore, such as, but not limited to,2-hydroxy-4-(3-triethoxysilylpropoxy)diphenylketone, a hydrolysate of2-hydroxy-4-(3-triethoxysilylpropoxy)diphenylketone, a co-hydrolysate of2-hydroxy-4-(3-triethoxysilylpropoxy)diphenylketone with at least oneother alkoxysilane. Compounds of this type have been used as UVstabilizers, but their use for this U.V. or opacifier purpose has notbeen previously studied. Additional silane- or siloxane-basedchromophores for use in the present invention includeO-4-methylcoumarinyl-N-[3-(triethoxysilyl)propylcarbamate], 3-(2,4-dinitrophenylamino)propyltriethoxysilane,7-triethoxysilylpropoxy-5-hydroxyflavone, andN-triethoxysilylpropyl-O-quinineurethane. In addition, derivatives andcombinations of the above-referenced silane- and siloxane-basedchromophores may be used within the scope of the invention.

The application of the silane of the present invention to transparent ortranslucent exterior surfaces including windows and other glasstreatments may be performed in any manner known in the art or to bedeveloped, as noted above. In such techniques it is preferred that thealkoxy groups in the silane- or siloxane-based compounds are displacedby hydroxy groups on the exterior-facing surface of the substratereceiving the coating. Alternatively, it is preferred that the compoundsare applied through use of a silanol-rich intermediate derived from asilane-or siloxane- alone, or by condensation with other such silanes orsiloxanes. Preferred UV-absorbing silane- or siloxane-basedchoromophores of this invention are those that absorb UV light at about350 nm to about 400 nm, with extinction coefficients greater than about50,000.

EXAMPLE 1

A 10% solution of 2-hydroxy-4-(3-triethoxysilylpropoxy)diphenylketone isprepared in tetrahydrofuran. Water in the amount of 1.5 molarequivalents is then added to the solution. The solution is aged twentyminutes to allow partial hydrolysis of the ethoxy groups. The solutionis then applied to at least a part of a transparent or translucentexterior surface, for example, a window, or other glass treatment, inthe form of an aerosol spray or a resin. A UV spectral analysis of thissolution in depicted in FIG. 2. At temperatures of about 15° to about30° C., a clear, anti-reflective layer may be optimally, and ispreferably, applied to the exterior facing surface of the UV-absorbingcoating. The anti-reflective layer may be in the form of a transparentmembrane and may be attached to the UV-absorbing layer by use of anadhesive bead, strip, tape, foam, sealant, or by chemical bonding. Suchcoated transparent exterior surfaces, such as windows and other glasstreatments, help to deter birds from collisions and resulting harm.

EXAMPLE 2

A 1 liter flask was equipped with a mechanical stirrer, pot thermometeraddition funnel and distillation head. It was charged with 460 g ofisopropanol, 113 g of methyltrimethoxysilane and 50 g ofdimethyldimethoxysilane, and stirring was commenced. To this, 37 g ofwater 0.1 g of tetramethylammonium hydroxide and 0.4 g of formic acidwere added rapidly, and the flask was heated to reflux until a clearsolution resulted. Approximately 150 g of a mixture of methanol andisopropanol were removed by distillation. The pot was allowed to cooland 5 weight percent of2-hydroxy-4-(3-triethoxysilylpropoxy)diphenylketone was added to thesolution.

EXAMPLE 3

The resin solution of the present solution was applied to glasssubstrates by dipping, resulting in a visually clear coating that curedto form an adherent film at room temperature. In some cases streakingwas observed. The streaking was eliminated by diluting the resinsolution with an equal volume of isopropanol.

It will be appreciated by those skilled in the art that changes could bemade to the embodiments described above without departing from the broadinventive concept thereof. It is understood, therefore, that thisinvention is not limited to the particular embodiments disclosed, but itis intended to cover modifications within the spirit and scope of thepresent invention as defined by the appended claims.

1-18. (canceled)
 19. A coated substrate, comprising (a) a transparentsubstrate having at least one surface including at least one exteriorfacing surface, and a coating on at least a portion of the at least oneexterior facing surface of the transparent substrate, wherein thecoating deters birds from colliding with the transparent substrate, andthe coating comprises: at least one of: (i) a silane- or siloxane-basedchromophore capable of forming stable bonds with the substrate,absorbing light at about 300 nm to about 400 nm and remainingtransparent to humans, wherein the silane- or siloxane-basedchromophore; and (ii) a composition comprising a silane and/or asiloxane and a chromophore, wherein the silane and/or siloxane iscapable of forming stable bonds with the substrate, and the chromophoreis capable of absorbing light at about 300 nm to about 400 nm, and (b)an anti-reflective layer on an exterior facing surface of the coating,wherein the coating is perceived as opaque by a bird but is perceived astransparent by humans when viewed from an interior or an exterior of thetransparent substrate.
 20. The coated substrate according to claim 19,wherein the silane- or siloxane-based chromophore is chosen from ahydroxyl diphenylketone or a derivative thereof.
 21. The coatedsubstrate according to claim 20, wherein the silane- or siloxane-basedchromophore is 2-hydroxy-4-(3-triethyoxysilylpropoxy)diphenylketone or aderivative thereof.
 22. The coated substrate according to claim 19,wherein the coating is applied by spraying, dip-coating, or film- orresin-coating techniques.
 23. The coated substrate according to claim19, wherein the anti-reflective layer is a transparent membrane.
 24. Thecoated substrate according to claim 19, wherein the anti-reflectivelayer is attached to the coating by at least one of an adhesive bead, astrip, a tape, a foam, a sealant, and a chemical bond.
 25. The coatedsubstrate according to claim 19, wherein the transparent substrate is aglass substrate and/or a window.
 26. The coated substrate according toclaim 19, wherein the silane- or siloxane-based chromophore absorbslight at about 325 nm to about 400 nm.
 27. The coated substrateaccording to claim 19, wherein the silane- or siloxane-based chromophoreis selected from the group consisting of a hydrolysate of2-hydroxy-4-(3-triethoxysilylpropoxy)diphenylketone, a co-hydrolysate of2-hydroxy-4-(3-triethoxysilylpropoxy)diphenylketone with at least oneother alkoxysilane,O-4-methylcoumarinyl-N-[3-(triethoxysilyl)propylcarbamate],3-(2,4-dinitrophenylamino)propyltriethoxysilane,7-triethoxysilylpropoxy-5-hydroxyflavone,N-triethoxysilylpropyl-O-quinineurethane and derivatives andcombinations thereof.
 28. The coated substrate according to claim 19,wherein the chromophore is capable of absorbing light at about 325 nm toabout 400 nm but does not absorb light in a range visually perceived byhumans.
 29. A coated substrate, comprising (a) a transparent substratehaving at least one surface including at least one exterior facingsurface and a coating on at least a portion of the at least one exteriorfacing surface of the transparent substrate, wherein the coating detersbirds from colliding with the transparent substrate, and the coatingcomprises: at least one of: (i) a silane- or siloxane-based chromophorecapable of forming stable bonds with the subtrate, and absorbing UVlight, wherein the silane- or siloxane-based chromophore is chosen fromhydroxyl diphenylketone or a derivative thereof; and (ii) a compositioncomprising a silane and/or a siloxane and a chromophore, wherein thesilane and/or siloxane is capable of forming stable bonds with thesubstrate, and the chromophore is capable of absorbing UV light, and (b)an anti-reflective layer on an exterior facing surface of the coating,wherein the coating is perceived as opaque by a bird but is perceived astransparent by humans when viewed from an interior or an exterior of thetransparent substrate.
 30. The coated substrate according to claim 29,wherein the silane- or siloxane-based chromophore is chosen fromhydroxyl diphenylketone or a derivative thereof.
 31. The coatedsubstrate according to claim 29, wherein the chromophore is capable ofabsorbing light at about 300 nm to about 400 nm.
 32. The coatedsubstrate according to claim 31, wherein the chromophore is capable ofabsorbing light at about 325 nm to about 400 nm.